Table 2. Limits of detection (LOD), limits of quantification (LOQ), linear equations, regression coefficients (r2) and recovery rates of PAHs determined with GC-MS

PAH compounds LOD (μg/kg) LOQ (μg/kg) Linear equation (y = a + bx) r2 Recovery (%)
Naphthalene 1.984 6.613 y = 10.383 + 0.680x 0.9948 114.86
Acenaphthylene 0.651 2.170 y = –0.570 + 0.807x 0.9987 100.10
Acenaphthene 0.991 3.303 y = 0.001 + 0.337x 0.9988 99.04
Fluorene 0.329 1.097 y = –0.064 + 0.384x 0.9991 96.22
Phenanthrene 0.332 1.107 y = 0.100 + 0.392x 0.9987 91.66
Anthracene 0.658 2.193 y = –0.290 + 0.372x 0.9982 93.50
Fluoranthene 0.495 1.650 y = –0.259 + 0.318x 0.9978 97.92
Pyrene 0.503 1.677 y = –0.306 + 0.360x 0.9977 97.74
Benzo[a]anthracene 1.347 4.490 y = –0.858 + 0.353x 0.9908 112.86
Chrysene 1.650 5.500 y = –0.343 + 0.431x 0.9961 107.62
Benzo[b]fluoranthene 0.990 3.300 y = –1.220 + 0.465x 0.9959 102.46
Benzo[k]fluoranthene 1.623 5.410 y = –1.668 + 0.631x 0.9912 104.48
Benzo[a]pyrene 1.155 3.850 y = –1.786 + 0.562x 0.9916 108.44
Indeno[1,2,3-cd]pyrene 1.287 4.290 y = –0.891 + 0.241x 0.9930 102.96
Dibenzo[a,h]anthracene 1.169 3.897 y = –0.987 + 0.237x 0.9936 99.84
Benzo[ghi]perylene 0.821 2.737 y = –0.692 + 0.257x 0.9938 104.84
PAHs, polycyclic aromatic hydrocarbons; GC-MS, gas chromatography–mass spectrometry.