Table 2. Limits of detection (LOD), limits of quantification (LOQ), linear equations, regression coefficients (r2) and recovery rates of PAHs determined with GC-MS
PAH compounds | LOD (μg/kg) | LOQ (μg/kg) | Linear equation (y = a + bx) | r2 | Recovery (%) |
Naphthalene | 1.984 | 6.613 | y = 10.383 + 0.680x | 0.9948 | 114.86 |
Acenaphthylene | 0.651 | 2.170 | y = –0.570 + 0.807x | 0.9987 | 100.10 |
Acenaphthene | 0.991 | 3.303 | y = 0.001 + 0.337x | 0.9988 | 99.04 |
Fluorene | 0.329 | 1.097 | y = –0.064 + 0.384x | 0.9991 | 96.22 |
Phenanthrene | 0.332 | 1.107 | y = 0.100 + 0.392x | 0.9987 | 91.66 |
Anthracene | 0.658 | 2.193 | y = –0.290 + 0.372x | 0.9982 | 93.50 |
Fluoranthene | 0.495 | 1.650 | y = –0.259 + 0.318x | 0.9978 | 97.92 |
Pyrene | 0.503 | 1.677 | y = –0.306 + 0.360x | 0.9977 | 97.74 |
Benzo[a]anthracene | 1.347 | 4.490 | y = –0.858 + 0.353x | 0.9908 | 112.86 |
Chrysene | 1.650 | 5.500 | y = –0.343 + 0.431x | 0.9961 | 107.62 |
Benzo[b]fluoranthene | 0.990 | 3.300 | y = –1.220 + 0.465x | 0.9959 | 102.46 |
Benzo[k]fluoranthene | 1.623 | 5.410 | y = –1.668 + 0.631x | 0.9912 | 104.48 |
Benzo[a]pyrene | 1.155 | 3.850 | y = –1.786 + 0.562x | 0.9916 | 108.44 |
Indeno[1,2,3-cd]pyrene | 1.287 | 4.290 | y = –0.891 + 0.241x | 0.9930 | 102.96 |
Dibenzo[a,h]anthracene | 1.169 | 3.897 | y = –0.987 + 0.237x | 0.9936 | 99.84 |
Benzo[ghi]perylene | 0.821 | 2.737 | y = –0.692 + 0.257x | 0.9938 | 104.84 |
PAHs, polycyclic aromatic hydrocarbons; GC-MS, gas chromatography–mass spectrometry.