Table 6 Estimated shelf life of pork lard (L) according to storage temperature using the Arrhenius equation
Quality indicator | Temperature (T) | Reaction order | Constant k1) | r2 | Ea2) (kcal/mol) | Q10 | Estimated shelf life (mon) |
AV | 283 | First | 0.0099 | r² =0.4893 | 6.35 | 1.47±0.13a | 10.17a |
298 | 0.0160 | r² =0.8431 | 1.42±0.10a | 5.76b |
308 | 0.0258 | r² =0.6243 | 1.39±0.24a | 4.07bc |
318 | 0.0331 | r² =0.6978 | 1.36±0.49a | 2.94c |
POV | 283 | Zero | 0.0439 | r² =0.9496 | 17.21 | 2.84±0.41a | 36.34a |
298 | 0.2263 | r² =0.9355 | 2.57±0.63a | 7.48b |
308 | 0.5503 | r² =0.9405 | 2.42±0.42a | 3.22c |
318 | 1.2760 | r² =0.9403 | 2.29±0.71a | 1.57d |
TBARS | 283 | Zero | 0.0011 | r² =0.9593 | 12.69 | 2.16±0.30a | 15.16a |
298 | 0.0046 | r² =0.9615 | 2.01±0.52a | 6.04b |
308 | 0.0071 | r² =0.8652 | 1.92±0.28a | 3.21c |
318 | 0.0138 | r² =0.9572 | 1.84±0.66a | 1.67c |
Sensory | 283 | Zero | 0.0070 | r² =0.7390 | 11.70 | 2.03±0.93a | 18.50a |
298 | 0.0220 | r² =0.8930 | 1.90±0.80a | 6.49b |
308 | 0.0400 | r² =0.9700 | 1.82±0.32a | 3.42c |
318 | 0.0690 | r² =0.9730 | 1.76±0.44a | 1.87d |
All values are mean standard deviation of three replicates.
a–d Means within a column with different letters are significantly different (p<0.05).
1) Rate constant.
2) Activation energy in kJ/mol.
AV, acid value; POV, peroxide value; TBARS, thiobarbituric acid reactive substances assay.